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CRDS line-shape study of the (7–0) band of CO

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dc.contributor.author Balashov, Aleksandr A.
dc.contributor.author Wójtewicz, Szymon
dc.contributor.author Domysławska, Jolanta
dc.contributor.author Ciuryło, Roman
dc.contributor.author Lisak, Daniel
dc.contributor.author Bielska, Katarzyna
dc.date.accessioned 2024-02-28T10:21:21Z
dc.date.available 2024-02-28T10:21:21Z
dc.date.issued 2024-02-28
dc.identifier.other https://doi.org/10.1016/j.saa.2024.124041
dc.identifier.uri http://repozytorium.umk.pl/handle/item/6993
dc.description.abstract We present the results of the spectral line-shape study of the first measurement of the extremely weak (7–0) band of the 12C16O molecule. Measurements were done with a highly sensitive cavity ring-down spectrometer. Collisional narrowing, analyzed in terms of speed-dependent effects, was observed for the first time for transitions with line intensities below 2 ⋅ 10−29 cm/molecule at 296 K. We provide a full set of line-shape parameters of the speed-dependent and regular Voigt profile analysis for 14 transitions from P and R branches. Experimental verification of a strong vibrational dependence of the pressure shifting described by the Hartmann model (Hartmann, 2009) is extended up to the sixth overtone highly sensitive to the model parameter.
dc.description.sponsorship The research was supported by the National Science Centre, Poland project no. 2018/30/E/ST2/00864, 2018/29/B/ST2/02974. S.W. was supported by the National Science Centre, Poland project No. 2021/42/E/ST2/00152. D.L. was supported by the National Science Centre, Poland project No. 2020/39/B/ST2/00719. The research was part of the program of the National Laboratory FAMO in Toruń, Poland.
dc.language.iso eng
dc.rights Attribution 4.0 Poland
dc.rights.uri https://creativecommons.org/licenses/by/4.0/deed.pl
dc.subject Carbon monoxide, Cavity ring-down spectroscopy, High resolution molecular spectroscopy, Spectral line shapes, Pressure broadening and shifting, Speed-dependent effects
dc.title CRDS line-shape study of the (7–0) band of CO
dc.type info:eu-repo/semantics/article


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